From this site you may download the kinetic model data, the
thermodynamic data, and the transport data using the link
below.
Download Mechanism
Based on the work:
"Laminar Flame Speeds and Oxidation Kinetics of
Tetrachloromethane" by J.C. Leylegian, C.K. Law, and H.
Wang. Twenty-Seventh Symposium (International) on Combustion,
pp. 529-536 (1998)
Abstract:
The laminar flame speeds of blends of tetrachloromethane (CCl4)
with methane in air at room temperature and atmospheric pressure
were experimentally determined using the counterflow twin-flame
technique, varying both the amount of CCl4 in the fuel and the
equivalence ratio of the unburned mixture.Flame speeds were
measured for stoichiometric mixtures with CCl4-to-CH4 ratios
between 0 and 0.429 by volume and for equivalence ratio ranges of
0.7-1.3 and 0.7-1.2 for CCl4-to-CH4 ratios of 0.053 and 0.200,
respectively. Comparison between the present experimental results
and the previous data of CH3Cl-, CH2Cl2-, and CHCl3-CH4-air flames
demonstrates the dominant influence of the atomic Cl-to-H ratio on
the propagation rate of laminar flames with chlorinated methane
addition. A detailed kineticmodel previously employed for CH3Cl,
CH2Cl2, and CHCl3 combustion was expanded to include
additionalpathways pertinent to tetrachloromethane combustion.
Numerical simulation shows that this modelpredicts the laminar
flame speeds reasonably well. Carbon flux and sensitivity analyses
indicate that theoxidation kinetics of CH4 flames doped with CCl4
are essentially the same as those doped with other
chloromethanes.